{"id":3384,"date":"2020-07-28T13:40:55","date_gmt":"2020-07-28T13:40:55","guid":{"rendered":"https:\/\/www.icsuro.com\/?p=3384"},"modified":"2023-11-30T18:16:29","modified_gmt":"2023-11-30T17:16:29","slug":"la-chimiluminescence-comme-controle-de-la-permeabilite-a-loxygene-des-bouchons","status":"publish","type":"post","link":"https:\/\/icsuro.com\/fr\/la-chimiluminescence-comme-controle-de-la-permeabilite-a-loxygene-des-bouchons\/","title":{"rendered":"La chimiluminescence comme contr\u00f4le de la perm\u00e9abilit\u00e9 \u00e0 l'oxyg\u00e8ne des bouchons"},"content":{"rendered":"

Comme indiqu\u00e9 dans l'article intitul\u00e9\u00a0"L'importance de la perm\u00e9abilit\u00e9 \u00e0 l'oxyg\u00e8ne"<\/a>\u00a0Publi\u00e9 dans le bulletin d'avril 2020 de la Fondation ICSURO, il existe plusieurs m\u00e9thodes pour d\u00e9terminer la perm\u00e9abilit\u00e9.<\/p>\n

Actuellement, il n'existe pas de m\u00e9thodologie \u00e9prouv\u00e9e et standardis\u00e9e pour la mesure de l'OTR et il est difficile d'\u00e9valuer les valeurs OTR pour diff\u00e9rents rev\u00eatements.<\/strong>. La premi\u00e8re technique d'analyse OTR pour les bouchons \u00e9tait le Mocon Oxtrans (Figure 1). Cette technique \u00e9tait bas\u00e9e sur la r\u00e9gulation des r\u00e9cipients en plastique ASTM-F107-14, en mesurant l'oxyg\u00e8ne qui \u00e9tait transf\u00e9r\u00e9 \u00e0 travers un goulot de bouteille scell\u00e9 \u00e0 une plaque m\u00e9tallique et en mesurant l'entr\u00e9e et la sortie des gaz par des techniques barom\u00e9triques. Cette technique pr\u00e9sente plusieurs limites, car elle est destructrice, co\u00fbteuse et avec une surveillance courte.<\/p>\n

\"Photo<\/a>
\n<\/a>Figure 1<\/strong>. Appareil de mesure de la perm\u00e9abilit\u00e9 des fermetures selon la m\u00e9thode Mocon. source Di\u00e9val, JB. et en 2011<\/em><\/p>\n

Des ann\u00e9es plus tard, d'autres techniques sont apparues comme celles bas\u00e9es sur le bisph\u00e9nol (Skouromounis et al 2007) ou colorim\u00e9triques (Lopes et al 2005) (figures 2 et 3). Les deux m\u00e9thodologies sont des techniques non destructives, mais elles n\u00e9cessitent un \u00e9quipement sp\u00e9cialis\u00e9 et co\u00fbteux, ce qui rend difficile leur utilisation en tant que techniques de routine. En m\u00eame temps, ils ne donnent pas de lectures directes mais n\u00e9cessitent une extrapolation \u00e0 un mod\u00e8le th\u00e9orique.<\/p>\n

\"Photo<\/a><\/p>\n

Figure 2<\/strong>. Appareil pour mesurer la perm\u00e9abilit\u00e9 des enceintes selon le bisph\u00e9nol. source Skouromounis et al. 2007.<\/em><\/p>\n

\"Photo<\/a><\/p>\n

figure 3<\/strong>. Sch\u00e9ma d'\u00e9talonnage de la m\u00e9thode colorim\u00e9trique bas\u00e9e sur la r\u00e9duction du carmin d'indigo. source Lopes, P. et al 2005 dans .J Agric. Chimie alimentaire.\u00a02005,\u00a0<\/strong>53, 6967-6973\u00a06967<\/strong><\/em><\/p>\n

Plus tard, la m\u00e9thode manom\u00e9trique a \u00e9t\u00e9 d\u00e9velopp\u00e9e, bas\u00e9e sur le passage d'air sous pression \u00e0 travers un morceau de li\u00e8ge de 3 mm (Lequin et al 2012) (figure 4). Cette technique a permis d'obtenir le coefficient de diffusion de O2<\/sub>\u00a0de ce mat\u00e9riau et non de l'OTR. Les r\u00e9sultats de cette technique sont difficiles \u00e0 extrapoler en tant que test de routine et il s\u2019agit \u00e9galement d\u2019une technique destructrice.<\/p>\n

\"Photo<\/a><\/p>\n

Figure 4<\/strong>. Sch\u00e9ma du manom\u00e8tre pour mesurer le transfert d'oxyg\u00e8ne \u00e0 travers le bouchon.. Source. Lequin, S. et al 2012. Dans J. Agric. Chimie alimentaire. 2012, 60, 3348\u22123356<\/em><\/p>\n

Enfin, la technique de chimiluminescence ou oxoluminescence a \u00e9t\u00e9 d\u00e9crite (Di\u00e9val\u00a0et autres<\/em>l. 2011).\u00a0La chimiluminescence est une m\u00e9thode non destructive et permet de suivre un bouchon au fil des mois en mesurant directement la quantit\u00e9 d'oxyg\u00e8ne \u00e0 l'int\u00e9rieur du flacon.<\/strong>\u00a0(Bunner et coll., 2010). Cette technique constitue la base th\u00e9orique des appareils d'oxoluminescence que l'on peut trouver sur le march\u00e9.<\/p>\n

L'appareil utilis\u00e9 dans le projet GO OTR s'appelle NOMASense et se compose d'un appareil \u00e9lectronique avec une sonde \u00e9mettrice et r\u00e9ceptrice.<\/strong>\u00a0(Fibox 3 LCD Trace V6), qui \u00e9met un flux lumineux ou une impulsion verte. Ce flux est dirig\u00e9 vers un capteur coinc\u00e9 \u00e0 l\u2019int\u00e9rieur du r\u00e9cipient transparent (bouteille). Le capteur est constitu\u00e9 de compos\u00e9s fluorescents qui absorbent l\u2019\u00e9nergie envoy\u00e9e par la sonde et la restituent sous forme de lumi\u00e8re. La mesure repose sur le fait que la concentration en oxyg\u00e8ne dans la bouteille est inversement proportionnelle au temps de retour de cette lumi\u00e8re. Le r\u00e9sultat est exprim\u00e9 directement sur l'\u00e9cran de l'appareil sous forme de pression partielle d'oxyg\u00e8ne \u00e0 l'int\u00e9rieur de la bouteille (PO2<\/sub>).<\/p>\n

\"Photo<\/a><\/p>\n

\"Photo<\/a><\/p>\n

Figure 5<\/strong>. NOMASense, appareil de mesures d'oxoluminescence. Source ICSURO.<\/em><\/p>\n

Le NOMASense est un appareil facile \u00e0 utiliser et peu co\u00fbteux qui mesure l'OTR des bouteilles pleines et vides au fil du temps (Figure 5). C\u2019est la technologie la plus proche de la r\u00e9alit\u00e9, les r\u00e9sultats obtenus peuvent donc \u00eatre extrapol\u00e9s. Ces avantages par rapport aux autres m\u00e9thodologies ont conduit les derniers articles publi\u00e9s sur l'OTR \u00e0 le plafonner (Chevalier\u00a0et coll.<\/em>\u00a02019).<\/p>\n

Dans le cadre de cette recherche, un groupe op\u00e9rationnel a \u00e9t\u00e9 cr\u00e9\u00e9 en 2017, compos\u00e9 de 4 entreprises produisant des bouchons du secteur catalan du li\u00e8ge. Deux de ces soci\u00e9t\u00e9s, J. VIGAS SA et MANUEL SERRA SA, produisent principalement des bouchons en li\u00e8ge naturel. Et les deux autres, TESA SA et FRANCISCO OLLER SA, produisent des bouchons en li\u00e8ge agglom\u00e9r\u00e9 \u00e0 deux disques pour le vin mousseux.\u00a0Le projet s'intitule \u00ab Projet pilote pour la d\u00e9termination de l'\u00e9volution de la perm\u00e9abilit\u00e9 \u00e0 l'oxyg\u00e8ne \u00e0 travers les diff\u00e9rentes conditions de fabrication des bouchons de li\u00e8ge et l'effet de ce param\u00e8tre sur les vins tranquilles et effervescents (GO OTR) \u00bb.<\/strong>.<\/p>\n

Le projet a permis de d\u00e9terminer les variables du processus de production qui affectent la perm\u00e9abilit\u00e9 \u00e0 l'oxyg\u00e8ne des bouchons et qui auront, de mani\u00e8re pr\u00e9visible, un effet significatif sur l'\u00e9volution des diff\u00e9rents types de vins et de vins mousseux.<\/p>\n

Il s'agit d'un projet cofinanc\u00e9 par le fonds europ\u00e9en FEDER et le D\u00e9partement de l'Agriculture, de l'\u00c9levage, de la P\u00eache et de l'Alimentation de la Generalitat de Catalogne \u00e0 travers l'Op\u00e9ration 16.01.01 (coop\u00e9ration pour l'innovation) du PDR de Catalogne 2014-2020.<\/p>\n

\"TH\u00c8SE\"<\/a>\"POUTRES\"<\/a>\"MANUEL_SERRA\"<\/a>\"REGARDER\"<\/a><\/p>\n

\"DARP\"<\/a><\/p>","protected":false},"excerpt":{"rendered":"

Comme indiqu\u00e9 dans l'article intitul\u00e9 \u00ab L'importance de la perm\u00e9abilit\u00e9 \u00e0 l'oxyg\u00e8ne \u00bb publi\u00e9 dans le bulletin d'information d'avril 2020 de la Fondation ICSURO, il existe plusieurs m\u00e9thodes pour d\u00e9terminer la perm\u00e9abilit\u00e9. Actuellement, il n\u2019existe aucune m\u00e9thodologie \u00e9prouv\u00e9e et standardis\u00e9e pour mesurer l\u2019OTR et il est difficile d\u2019\u00e9valuer les valeurs OTR pour diff\u00e9rents rev\u00eatements. [\u2026]<\/p>","protected":false},"author":5,"featured_media":7773,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[242],"tags":[10,253,23],"class_list":["post-3384","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-sin-categorizar","tag-investigacio","tag-quimioluminiscencia","tag-taps-de-suro"],"yoast_head":"\nLa quimioluminesc\u00e8ncia com a control de permeabilitat a l\u2019oxigen dels taps de suro - Icsuro<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/icsuro.com\/fr\/la-chimiluminescence-comme-controle-de-la-permeabilite-a-loxygene-des-bouchons\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"La quimioluminesc\u00e8ncia com a control de permeabilitat a l\u2019oxigen dels taps de suro - Icsuro\" \/>\n<meta property=\"og:description\" content=\"Tal com es comentava a l\u2019article titulat\u00a0\u201cLa import\u00e0ncia de la permeabilitat a l\u2019oxigen\u201d\u00a0publicat a la newsletter\u00a0del mes d’abril de 2020 de\u00a0la Fundaci\u00f3 ICSURO, existeixen diversos m\u00e8todes per determinar la permeabilitat. 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